Convenient synthesis of ethyl 4-aryl-6-(trifluoromethyl)-2-oxo-2H-pyran-3-carboxylates and 4-aryl-6-(trifluoromethyl)-2H-pyran-2-ones: Novel highly reactive CF(3)-containing building blocks / Usachev Boris I.,Obydennov Drnitrii L.,Roeschenthaler Gerd-Volker,Sosnovskikh Vyacheslav Ya. // ORGANIC LETTERS. - 2008. - V. 10, l. 13. - P. 2857-2859.

ISSN/EISSN:

1523-7060 / нет данных

Type:

Article

Abstract:

An expedient synthesis of a series of 2-pyrones, bearing a CF(3) group at the 6-position and aryl group at position 4, from readily available aryl-4,4,4-trifluorobutane-1,3-diones, PCl(5), and sodium diethyl malonate is described.

Author keywords:

ALDER IEDDA REACTIONS; 3-CARBOMETHOXY-2-PYRONE 3-CMP; ORGANIC POLYHALIDES; DERIVATIVES; ADDITIONS; OLEFINS

DOI:

10.1021/ol800992z

Web of Science ID:

ISI:000257211400061

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUL 3
Publisher	AMER CHEMICAL SOC
Address	1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Language	English
Keywords-Plus	ALDER IEDDA REACTIONS; 3-CARBOMETHOXY-2-PYRONE 3-CMP; ORGANIC POLYHALIDES; DERIVATIVES; ADDITIONS; OLEFINS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	boris.usachev@mail.ru
Number-of-Cited-References	16
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	6
Journal-ISO	Org. Lett.
Doc-Delivery-Number	320CN