A novel redox reaction between 8-aza-5,7-dimethyl-2-trifluoromethylchromone and alkyl mercaptoacetates / Sosnovskikh VY,Barabanov MA,Usachev BI // ORGANIC LETTERS. - 2003. - V. 5, l. 14. - P. 2501-2504.

ISSN/EISSN:

1523-7060 / нет данных

Type:

Article

Abstract:

{[}GRAPHICS] B-Aza-5,7-dimethyl-2-trifluoromethylchromone reacts with alkyl mercaptoacetates to give pyrido derivatives of 2-oxa-7-thiabicyclo{[}3.2.1]octane, which undergo the reductive ring-opening to sulfanyl acetates. The latter compounds are useful CF3-containing building blocks for the preparation of a variety of 2-pyridone derivatives.

Author keywords:

ETHYL MERCAPTOACETATE; DERIVATIVES; 1,1,1-TRIFLUORO-2-PENTEN-4-ONE; 7-POLYFLUOROALKYLNORKHELLINS; KETONES

DOI:

10.1021/ol034766q

Web of Science ID:

ISI:000183988300033

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUL 10
Publisher	AMER CHEMICAL SOC
Address	1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Language	English
Keywords-Plus	ETHYL MERCAPTOACETATE; DERIVATIVES; 1,1,1-TRIFLUORO-2-PENTEN-4-ONE; 7-POLYFLUOROALKYLNORKHELLINS; KETONES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	vyacheslav.sosnovskikh@usu.ru
Number-of-Cited-References	21
Usage-Count-Since-2013	2
Journal-ISO	Org. Lett.
Doc-Delivery-Number	698FU