Reactions of aromatic methyl ketimines with halonitriles as a new route to pyrimidines with two polyhaloalkyl groups / Sosnovskikh VY,Usachev BI,Roschenthaler GV // TETRAHEDRON. - 2002. - V. 58, l. 7. - P. 1375-1379.

ISSN/EISSN:

0040-4020 / нет данных

Type:

Article

Abstract:

N-Isopropyl-(1-phenylethylidene)amine reacts with trichloroacetonitrile to give 1-azabutadiene derivative, which undergoes a double addition reaction with a variety of halonitriles affording fluoro- and chloro-containing pyrimidines. Pyrimidines with two poly-haloalkyl groups were obtained by the reaction of methyl ketimines with an excess of trichloroacetonitrile, trifluoroacetonitrile and 2,2,3,3-tetrafluoropropionitrile. (C) 2002 Elsevier Science Ltd. All rights reserved.

Author keywords:

methyl ketimines; trichloroacetonitrile; trifluoroacetonitrile; 2,2,3,3-tetrafluoro-propionitrile; CCl3-containing beta-aminovinyl imine and ketone; pyrimidines with two polyhaloalkyl groups HALOACETYLATED ENOL ETHERS; BETA-ENAMINO KETONES; CONDENSATION; NITRILES; TRICHLOROACETONITRILES; TRIFLUOROACETONITRILES; DERIVATIVES

DOI:

10.1016/S0040-4020(01)01231-5

Web of Science ID:

ISI:000174339600015

Соавторы в МНС:

Другие поля

Поле	Значение
Month	FEB 11
Publisher	PERGAMON-ELSEVIER SCIENCE LTD
Address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language	English
Article-Number	PII S0040-4020(01)01231-5
Keywords-Plus	HALOACETYLATED ENOL ETHERS; BETA-ENAMINO KETONES; CONDENSATION; NITRILES; TRICHLOROACETONITRILES; TRIFLUOROACETONITRILES; DERIVATIVES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Number-of-Cited-References	40
Usage-Count-Since-2013	3
Journal-ISO	Tetrahedron
Doc-Delivery-Number	530DD