Synthesis and reactions of 2-hydroxy-5,5-dimethyl- and 2-hydroxy-5,5-pentamethylene-2-trifluoromethyltetrahydro-4-pyranones with N-nucleophiles / Sosnovskikh VY,Mel'nikov MY,Zaitsev AV,Bogdanov EA // RUSSIAN CHEMICAL BULLETIN. - 1998. - V. 47, l. 6. - P. 1170-1174.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

Condensation of 4-hydroxy-3,3-dimethyl- and 4-hydroxy-3,3-pentamethylenebutan-2-ones with ethyl trifluoroacetate in the presence of LiH in hexane afforded 2-hydroxy-5,5-dimethyl- and 2-hydroxy-5,5-pentamethylene-2-trifluoromethyltetrahydro-4-pyranones, whose behavior in reactions with N-nucleophiles is analogous to that of unsymmetrical polyfluorinated beta-diketones.

Author keywords:

condensation; beta-hydroxyketones; ethyl trifluoroacetate; tetrahydro-4-pyranones; aminoenones; CF3-containing pyrazoles and Delta(2)-isoxazolines

DOI:

10.1007/BF02503492

Web of Science ID:

ISI:000075138600024

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	JUN
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU, 233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	Vyacheslav.Sosnovskikh@usu.ru
Number-of-Cited-References	7
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	106PT