Stability of the Mo72Fe30 polyoxometalate buckyball in solution / Ostroushko A. A.,Tonkushina M. O.,Korotaev V. Yu,Prokof'eva A. V.,Kutyashev I. B.,Vazhenin V. A.,Danilova I. G.,Men'shikov S. Yu // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2012. - V. 57, l. 9. - P. 1210-1213.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

The stability of the {[}Mo72Fe30O252(CH3COO)(12)\{Mo2O7(H2O)\}(2)\{H2Mo2O8(H2O)\}(H2O)(91)] center dot similar to 150H(2)O polyoxometalate (Mo72Fe30) with a buckyball framework structure in solution has been investigated as a function of the solute concentration, illuminance, the presence/absence of a polymer, and the acidity of the medium. The polyoxometalate ions can form association species with molecules of water-soluble nonionic polymers, such as polyvinyl alcohol and polyvinylpyrrolidone. Electrotransport properties of the polyoxometalate ions-mobility, transport number, and diffusion coefficient-have been measured. The catalytic activity and stability of Mo72Fe30 in a redox reaction have been evaluated.

Author keywords:

COMPOSITIONS BASED THEREON; MOLYBDENUM-OXIDE

DOI:

10.1134/S0036023612090173

Web of Science ID:

ISI:000308427300006

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	COMPOSITIONS BASED THEREON; MOLYBDENUM-OXIDE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Danilova, Irina/A-7952-2015 Tonkushina, Margarita/D-8463-2012 Korotaev, Vladislav/L-2692-2016
ORCID-Numbers	Tonkushina, Margarita/0000-0003-4371-3900 Korotaev, Vladislav/0000-0002-7492-5116
Funding-Acknowledgement	Russian Foundation for Basic Research {[}10-03-00799]; Federal Target Program ``Scientific and Scientific-Pedagogical Personnel of Innovative Russia{''}
Funding-Text	This study was supported by the Russian Foundation for Basic Research (grant no. 10-03-00799) and by the Federal Target Program ``Scientific and Scientific-Pedagogical Personnel of Innovative Russia{''} for 2009-2012.
Number-of-Cited-References	15
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	31
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	000YP