Retrograde solubility in the Cu-TiTe2 system / Titov A. A.,Titov A. N.,Titova S. G. // PHYSICS OF THE SOLID STATE. - 2014. - V. 56, l. 10. - P. 2087-2091.

ISSN/EISSN:

1063-7834 / 1090-6460

Type:

Article

Abstract:

Intercalate materials, which exhibit retrograde solubility without variation in the aggregate state, are of interest for the formation of nanostructured composites, since they make it possible to perform the decomposition at a relatively low temperature and to obtain stable nanoinclusions. In order to broaden the range of such materials, a new Cu-TiTe2 intercalate system is synthesized. The crystal structure and the temperature dependence of solubility of copper are investigated. It is shown that the enhancement of the covalent component of the intercalant-lattice chemical bond as compared to the Cu (x) TiSe2 system leads to the retrograde solubility character.

Author keywords:

FE X TISE2; INTERCALATION COMPOUND; PHOTOEMISSION-SPECTROSCOPY; POLARON SHIFT; PHASE-DIAGRAM; FEXTITE2; STATE

DOI:

10.1134/S1063783414100308

Web of Science ID:

ISI:000343715600024

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	OCT
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1090-6460
Keywords-Plus	FE X TISE2; INTERCALATION COMPOUND; PHOTOEMISSION-SPECTROSCOPY; POLARON SHIFT; PHASE-DIAGRAM; FEXTITE2; STATE
Research-Areas	Physics
Web-of-Science-Categories	Physics, Condensed Matter
Author-Email	antitov@mail.ru
ResearcherID-Numbers	Titova, Svetlana/D-2316-2013 Titov, Alexander/K-4328-2013
ORCID-Numbers	Titov, Alexander/0000-0003-3636-2604
Funding-Acknowledgement	Presidium of the Ural Branch of the Russian Academy of Sciences {[}12-M-23-2031]; Russian Foundation for Basic Research {[}14-03-00274]
Funding-Text	This study was performed using the equipment of the Ural-M Collective Use Center at the Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences and supported by the Presidium of the Ural Branch of the Russian Academy of Sciences (interdisciplinary project no. 12-M-23-2031) and the Russian Foundation for Basic Research (project no. 14-03-00274).
Number-of-Cited-References	19
Usage-Count-Last-180-days	4
Usage-Count-Since-2013	33
Journal-ISO	Phys. Solid State
Doc-Delivery-Number	AR6TI