MxTiSe2 (M=Cr, Mn, Cu) electronic structure study by methods of resonance X-ray photoemission spectroscopy and X-ray absorption spectroscopy / Shkvarin A. S.,Yarmoshenko Yu. M.,Yablonskikh M. V.,Skorikov N. A.,Merentsov A. I.,Kuznetsov M. V.,Titov A. N. // JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS. - 2012. - V. 73, l. 12, SI. - P. 1562-1565.

ISSN/EISSN:

0022-3697 / нет данных

Type:

Article; Proceedings Paper

Abstract:

Intercalation of Cu and Mn between the layers of TiSe2 leads to the charge transfer from the doped atom to Ti atoms, electronic states of which form the conduction band of TiSe2. This situation drastically differs from another one being observed during intercalation of other transition metals into TiSe2 that leads to the formation of covalent complexes consisting of intercalated atom and nearest neighborhood of the host lattice. Substitution of Ti by Cr in the host lattice positions does not show both charge transfer nor formation of covalent complexes. (C) 2012 Elsevier Ltd. All rights reserved.

Author keywords:

Photoelectron spectroscopy; Electronic structure TRANSITION-METAL DICHALCOGENIDES; MAGNETIC-PROPERTIES

DOI:

10.1016/j.jpcs.2012.04.012

Web of Science ID:

ISI:000310925900038

Соавторы в МНС:

Другие поля

Поле	Значение
Month	DEC
Note	16th International Symposium on Intercalation Compounds (ISIC), CZECH REPUBLIC, MAY, 2011
Publisher	PERGAMON-ELSEVIER SCIENCE LTD
Address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language	English
Keywords-Plus	TRANSITION-METAL DICHALCOGENIDES; MAGNETIC-PROPERTIES
Research-Areas	Chemistry; Physics
Web-of-Science-Categories	Chemistry, Multidisciplinary; Physics, Condensed Matter
Author-Email	shkvarin@ifmlrs.uran.ru
ResearcherID-Numbers	Titov, Alexander/K-4328-2013 Merentsov, Alexander/R-6275-2016 Yarmoshenko, Yuri/E-9531-2011 Kuznetsov, Mikhail/N-4007-2014 Shkvarin, Alexey/J-4275-2013 Skorikov, Nikolay/A-6728-2012
ORCID-Numbers	Titov, Alexander/0000-0003-3636-2604 Merentsov, Alexander/0000-0002-0005-2594 Yarmoshenko, Yuri/0000-0001-8971-2052 Kuznetsov, Mikhail/0000-0002-4464-0355 Shkvarin, Alexey/0000-0002-3774-5669 Skorikov, Nikolay/0000-0002-3771-8708
Number-of-Cited-References	15
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	64
Journal-ISO	J. Phys. Chem. Solids
Doc-Delivery-Number	035EL