Fast ionic transport in Ag (x) TiS2 / Titov A. N. // PHYSICS OF THE SOLID STATE. - 2009. - V. 51, l. 4. - P. 714-720.

ISSN/EISSN:

1063-7834 / нет данных

Type:

Article

Abstract:

The enthalpy of the subsystem of silver ions in the intercalation compounds Ag (x) TiS2 has been calculated from the electrochemically measured thermodynamic functions of the silver subsystem. The ionic conductivity and the coupled chemical diffusion coefficients for silver in the intercalation compound have been measured. The activation energy for diffusion of silver ions is determined and the obtained value is interpreted from analyzing the concentration dependence of the enthalpy of the ionic subsystem. The conclusion has been drawn that the high diffusion mobility is associated with the competition between the covalent and elastic interactions, which decreases the activation energy for diffusion of ions.

Author keywords:

INTERCALATION COMPOUNDS; AGXTIS2

DOI:

10.1134/S1063783409040106

Web of Science ID:

ISI:000265651100010

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	APR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	INTERCALATION COMPOUNDS; AGXTIS2
Research-Areas	Physics
Web-of-Science-Categories	Physics, Condensed Matter
Author-Email	alexander.titov@usu.ru
ResearcherID-Numbers	Titov, Alexander/K-4328-2013
ORCID-Numbers	Titov, Alexander/0000-0003-3636-2604
Funding-Acknowledgement	Russian Foundation for Basic Research {[}06-03-32900]
Funding-Text	This study was supported by the Russian Foundation for Basic Research (project nos. 06-03-32900).
Number-of-Cited-References	13
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	20
Journal-ISO	Phys. Solid State
Doc-Delivery-Number	439TX