Lead-selective electrode based on the misfit compound (PbS)(1.18)TiS2 / Velikanova TV,Titov AN,Shishmintseva NN // JOURNAL OF ANALYTICAL CHEMISTRY. - 2000. - V. 55, l. 11. - P. 1051-1054.

ISSN/EISSN:
1061-9348 / нет данных
Type:
Article; Proceedings Paper
Abstract:
A lead-selective solid-contact electrode was prepared on the basis of the misfit compound (PbS)(1.18)TiS2 The electrode exhibits the slope of the electrode function is -(26 +/- 1) mV/pc and provides the determination of 1 x 10(-5)-5 x 10(-2) M lead in the pH range 2.75-5.0. High selectivity of the electrode for Ni2+ Co2+, Zn2+, Cu2+, Ag+, K+, Ba2+, and Sr2+ ions was demonstrated. The addition of graphite to the active phase of the membrane impaired the selectivity of the electrode. The electrode was used for the potentiometric indication of the titration end point in the determination of lead in copper alloys.
Author keywords:
нет данных
DOI:
10.1007/BF02757330
Web of Science ID:
ISI:000165318100009
Соавторы в МНС:
Другие поля
Поле Значение
Month NOV
Note Vth All Russian Conference on Electrochemical Methods of Analysis (EMA-99), MOSCOW, RUSSIA, DEC 06-08, 1999
Publisher MAIK NAUKA/INTERPERIODICA
Address C/O KLUWER ACADEMIC-PLENUM PUBLISHERS, 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language English
Research-Areas Chemistry
Web-of-Science-Categories Chemistry, Analytical
ResearcherID-Numbers Titov, Alexander/K-4328-2013
ORCID-Numbers Titov, Alexander/0000-0003-3636-2604
Number-of-Cited-References 8
Usage-Count-Since-2013 3
Journal-ISO J. Anal. Chem.
Doc-Delivery-Number 373YR