Structural, Optical Properties, and Biological Activity of Complexes Based on Derivatives of Quinoline, Quinoxaline, and Quinazoline with Metal Centers from Across the Periodic Table / Lipunova Galina N.,Nosova Emiliya V.,Charushin Valery N.,Chupakhin Oleg N. // COMMENTS ON INORGANIC CHEMISTRY. - 2014. - V. 34, l. 5-6. - P. 142-177.

ISSN/EISSN:

0260-3594 / 1548-9574

Type:

Review

Abstract:

This review is focused on consideration of the influence of ligands and synthetic conditions on the structure and optical properties of a variety of metal complexes based on derivatives of quinoline, quinoxaline, and quinazoline. It has been established that changing of substituents in a given ligand provides an opportunity to tune color and intensity of the photoluminescence of the corresponding Al(III) and Zn(II) complexes, while variation of auxiliary ligands in cyclometalated complexes leads to emission emergence at ambient temperature. Difluoroboron complexes of metals with N,O-bidentate ligands proved to exhibit a strong photoluminescence in both solutions and the solid state. Some complexes of this type are useful for electroluminescent or solar cell devices. Biological activity of quinoline complexes is governed mainly by the metal nature.

Author keywords:

quinolines; cyclometalated derivatives; biological activity; photoluminescence; quinoxalines; quinazolines; BF2-complexes SENSITIZED SOLAR-CELLS; FLUORESCENT BF2 COMPLEXES; LIGHT-EMITTING-DIODES; CRYSTAL-STRUCTURE; COPPER(II) COMPLEXES; 8-HYDROXYQUINOLINE DERIVATIVES; ELECTROLUMINESCENT DIODES; PHOTOPHYSICAL PROPERTIES; PHOTOVOLTAIC PROPERTIES; COORDINATION POLYMER

DOI:

10.1080/02603594.2014.959116

Web of Science ID:

ISI:000345073700002

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP 2
Publisher	TAYLOR \& FRANCIS LTD
Address	4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND
Language	English
EISSN	1548-9574
Keywords-Plus	SENSITIZED SOLAR-CELLS; FLUORESCENT BF2 COMPLEXES; LIGHT-EMITTING-DIODES; CRYSTAL-STRUCTURE; COPPER(II) COMPLEXES; 8-HYDROXYQUINOLINE DERIVATIVES; ELECTROLUMINESCENT DIODES; PHOTOPHYSICAL PROPERTIES; PHOTOVOLTAIC PROPERTIES; COORDINATION POLYMER
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Author-Email	emily74@rambler.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}14-03-00340]; Ural Division of Russian Academy of Sciences {[}12-P-3-1020]; Grants Council of the President of the Russian Federation {[}NSh-3656.2014.3]
Funding-Text	This work was supported by the Russian Foundation for Basic Research (grant 14-03-00340) and Ural Division of Russian Academy of Sciences (project 12-P-3-1020), as well as the Grants Council of the President of the Russian Federation (grant NSh-3656.2014.3).
Number-of-Cited-References	90
Usage-Count-Last-180-days	6
Usage-Count-Since-2013	41
Journal-ISO	Comments Inorganic Chem.
Doc-Delivery-Number	AT6UC