Cyclic peroxides and related initiating systems for radical polymerization of methyl methacrylate / Islamova R. M.,Ishkinina O. I.,Nazarova S. V.,Chupakhin O. N.,Utepova I. A.,Andriyashina N. M.,Terent'ev A. O. // RUSSIAN CHEMICAL BULLETIN. - 2013. - V. 62, l. 5. - P. 1282-1285.

ISSN/EISSN:

1066-5285 / 1573-9171

Type:

Article

Abstract:

Cyclic peroxides as initiators for the radical polymerization of methyl methacrylate were proposed. The initial rates, initiation rates, and effective activation energies of polymerization initiated by cyclic peroxides and cyclic peroxide-1-pyridyl-2-ferrocene systems were deter-mined. The radical yields to the volume upon the thermal decomposition of cyclic peroxides and their catalytic decomposition in the presence of 1-pyridyl-2-ferrocene were determined. In combination with 1-pyridyl-2-ferrocene cyclic peroxides form efficient initiating systems favoring an increase in the polymerization rate, a decrease in the molecular weights, and an increase in syndiotacticity of the synthesized poly(methyl methacrylate).

Author keywords:

radical polymerization; cyclic peroxides; initiators; 1-pyridyl-2-ferrocene; initiating systems; kinetic parameters; molecular characteristics FERROCENE

DOI:

нет данных

Web of Science ID:

ISI:000332793600022

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAY
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
EISSN	1573-9171
Keywords-Plus	FERROCENE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	rmislamova@mail.ru
ResearcherID-Numbers	Islamova, Regina/E-1849-2014
ORCID-Numbers	Islamova, Regina/0000-0003-1180-6539 Terent'ev, Alexander/0000-0001-8018-031X Andriyashina, Nadezhda/0000-0002-1985-4394
Number-of-Cited-References	19
Usage-Count-Last-180-days	7
Usage-Count-Since-2013	12
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	AC8OQ