Effect of heterocyclic derivatives of ferrocene on free-radical polymerization of methyl methacrylate and styrene / Islamova R. M.,Golovochesova O. I.,Monakov Yu B.,Utepova I. A.,Musikhina A. A.,Chupakhin O. N. // POLYMER SCIENCE SERIES B. - 2010. - V. 52, l. 11-12. - P. 637-647.

ISSN/EISSN:

1560-0904 / нет данных

Type:

Article

Abstract:

The free-radical bulk homopolymerization of methyl methacrylate and styrene initiated by benzoyl peroxide or AIBN in the presence of heterocyclic derivatives of ferrocene is studied. It is shown that, in the case of the peroxide initiator, ferrocene derivatives form highly efficient initiation systems, which make it possible to polymerize methyl methacrylate at a high rate, to reduce the molecular mass of polymers, and to synthesize polymers with a high content of syndiotactic triads, while in the case of AIBN, such systems are not formed.

Author keywords:

нет данных

DOI:

10.1134/S1560090410110023

Web of Science ID:

ISI:000286001500002

Соавторы в МНС:

Другие поля

Поле	Значение
Month	DEC
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Polymer Science
Web-of-Science-Categories	Polymer Science
Author-Email	puzin@anrb.ru
ResearcherID-Numbers	Islamova, Regina/E-1849-2014
ORCID-Numbers	Islamova, Regina/0000-0003-1180-6539
Funding-Acknowledgement	Russian Foundation for Basic Research {[}10-03-00027-a, 07-03-96104r\_ural\_a]; Russian Federation {[}MK-4166.2009.3]
Funding-Text	This work was supported by the Russian Foundation for Basic Research (project nos. 10-03-00027-a and 07-03-96104r\_ural\_a) and a grant from the president of the Russian Federation for Supporting Young Scientists (project MK-4166.2009.3).
Number-of-Cited-References	13
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	9
Journal-ISO	Polym. Sci. Ser. B
Doc-Delivery-Number	703SL