Fluoro-containing heterocycles. IV. Synthesis of benzimidazole derivatives / Kotovskaya SK,Perova NM,Baskakova ZM,Romanova SA,Charushin VN,Chupakhin ON // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2001. - V. 37, l. 4. - P. 564-569.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

2-Mercapto-5,6-difluorobenzimidazole reacts with aliphatic and alicyclic ketones in acetic acid in the presence of catalytic amount of sulfuric acid to afford fluorinated derivatives of 2,3-disubstituted benz{[}4,5]imidazo{[}2,1-b]{[}1,3]thiazoles. Reaction with aromatic alpha -haloketones Occurs in another way: to furnish 2-phenylacylthio-5,6-difluorobenzimidazoles that in the system acetic anhydride-pyridine undergo cyclization into the corresponding fluorinated derivatives of benz{[}4,5]imidazo{[}2,1-b]{[}1,3]thiazoles.

Author keywords:

нет данных

DOI:

10.1023/A:1012446305955

Web of Science ID:

ISI:000170630600016

Соавторы в МНС:

Другие поля

Поле	Значение
Month	APR
Publisher	MAIK NAUKA/INTERPERIODICA
Address	C/O KLUWER ACADEMIC-PLENUM PUBLISHERS, 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Number-of-Cited-References	15
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	466ED