Supramolecular structural design in a system based on nanocluster Mo-138 and a cationic surfactant: The influence of components ratio and pH of the solution / Grzhegorzhevskii Kirill Valentinovich,Ostroushko Alexander Alexsandrovich // COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS. - 2015. - V. 480, l. . - P. 130-137.

ISSN/EISSN:

0927-7757 / 1873-4359

Type:

Article

Abstract:

The design of supramolecular compounds is one of the key modern chemical trends. Based on the study of self-organising processes, supramolecular chemistry allows the creation of complex nanoclustered and hierarchical structures by the self-assembly method. We have investigated a system consisting of nanoclustered polyoxomolybdate Mo-138 with a toroid structure and cationic surfactant n-tridecylpyridinium chloride (TDPCh). As a result, the peculiarity of adsorptive interaction between system components was uncovered. This interaction depends on the components ratio and the pH of the solution and leads to spontaneous formation of hierarchical supramolecular structures. The sizes of ion-associates \{(Mo-138)(x)-(TDPCh)(y)\

Author keywords:

Supramolecular structure; Nanocluster; Surfactant; Self-assembly; Ion-associate; Association MOLYBDENUM-OXIDE; KEPLERATE-TYPE; POLYOXOMOLYBDATES; BLUE

DOI:

10.1016/j.colsurfa.2015.03.012

Web of Science ID:

ISI:000356051200017

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP 5
Publisher	ELSEVIER SCIENCE BV
Address	PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Language	English
EISSN	1873-4359
Keywords-Plus	MOLYBDENUM-OXIDE; KEPLERATE-TYPE; POLYOXOMOLYBDATES; BLUE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Physical
Author-Email	kirillica5@mail.ru alexandre.ostroushko@usu.ru
ResearcherID-Numbers	Grzhegorzhevskii, Kirill/H-2978-2012
ORCID-Numbers	Grzhegorzhevskii, Kirill/0000-0003-3357-9672
Funding-Acknowledgement	Ural Federal University development program; Ministry of Education and Science of the Russian Federation {[}2343]
Funding-Text	The research was carried as part of the Ural Federal University development program with the financial support of young scientists, Also we express thank to Ministry of Education and Science of the Russian Federation (project code 2343).
Number-of-Cited-References	11
Usage-Count-Last-180-days	3
Usage-Count-Since-2013	22
Journal-ISO	Colloid Surf. A-Physicochem. Eng. Asp.
Doc-Delivery-Number	CK2OU