Interaction of keplerate-type molybdenum-based porous spherical nanoclusters with polymer macromolecules / Ostroushko A. A. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2015. - V. 60, l. 3. - P. 387-391.

ISSN/EISSN:

0036-0236 / 1531-8613

Type:

Article

Abstract:

Characteristics of aqueous solutions of keplerate-type nanocluster polyoxomolybdates (POMs) and water-soluble nonionogenic polymers (polyvinyl alcohol, polyvinylpyrrolidone), such as dynamic viscosity, optical density, and aggregate particle size, have been compared. It has been shown that physicochemical properties of solutions in which POM associates with polymer macromolecules are formed are a nonlinear function of the component ratio. Oscillations of the above parameters are associated with the non-random character of interaction between the solution components and its change in the course of successive increase in the relative concentration of sorbate polymer molecules.

Author keywords:

POLY(VINYL ALCOHOL); POLYVINYL-ALCOHOL; OXIDE; COMPLEXES; POLYOXOMETALATE; FULLERENE; CLUSTERS; ENTHALPY

DOI:

10.1134/S0036023615030158

Web of Science ID:

ISI:000351695300019

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	MAR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1531-8613
Keywords-Plus	POLY(VINYL ALCOHOL); POLYVINYL-ALCOHOL; OXIDE; COMPLEXES; POLYOXOMETALATE; FULLERENE; CLUSTERS; ENTHALPY
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Author-Email	alexander.ostroushko@urfu.ru
Number-of-Cited-References	35
Usage-Count-Since-2013	13
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	CE3AH