Destruction of molybdenum nanocluster polyoxometallates in aqueous solutions / Ostroushko A. A.,Tonkushina M. O. // RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A. - 2015. - V. 89, l. 3. - P. 443-446.

ISSN/EISSN:

0036-0244 / 1531-863X

Type:

Article

Abstract:

The kinetics of the decomposition of nanocluster polyoxomolybdate (POM) with a keplerate structure Mo72Fe30 and toroidal POMs Mo-138 in aqueous solutions was studied. The POM concentration was determined by spectrophotometry. The limiting stage of the destruction was concluded to be the decomposition of free keplerate molecules (ions) or the keplerates of aggregates (globules).

Author keywords:

polyoxometallates; nanoclusters; decomposition kinetics; keplerates COMPOSITIONS BASED THEREON; BUCKYBALL STRUCTURE; OXIDE; POLYOXOMOLYBDATES; IONS

DOI:

10.1134/S003602441503022X

Web of Science ID:

ISI:000349295400016

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1531-863X
Keywords-Plus	COMPOSITIONS BASED THEREON; BUCKYBALL STRUCTURE; OXIDE; POLYOXOMOLYBDATES; IONS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Physical
Author-Email	Alexandre.Ostroushko@usu.ru
Funding-Acknowledgement	Ministry of Science and Education of the Russian Federation; program for young scientists of the Ural Branch, Russian Academy of Sciences {[}14-4-NP-327]
Funding-Text	This study was financially supported by the Ministry of Science and Education of the Russian Federation and the program for young scientists of the Ural Branch, Russian Academy of Sciences (grant no. 14-4-NP-327, 2014). We are grateful to A. V. Prokofieva and A.Ya. Golub for their help with spectrophotometric measurements.
Number-of-Cited-References	31
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	13
Journal-ISO	Russ. J. Phys. Chem. A
Doc-Delivery-Number	CB0DL