Molybdenum polyoxometalate buckyballs containing monochloroacetate groups and polymer compositions on their base / Ostroushko A. A.,Tonkushina M. O.,Safronov A. P.,Udilov A. E. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2010. - V. 55, l. 8. - P. 1260-1265.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

Molybdenum polyoxometalate buckyballs (NH(4))(42){[}MO (72) (VI) MO (60) (V) O(372)(ClCH(2)COO)(30)(H(2)O)(72)] center dot 250H(2)O center dot 15ClCH(2)COONa (Mo132Cl) were synthesized; some of their properties were studied, namely, purity, spectral and crystallographic parameters, buckyball aggregation in solution, and interaction with water-soluble nonionic polymers (poly(vinyl alcohol) and poly(vinylpyrrolidone)). The newly synthesized polyoxometalate was shown to have a lower stability than its analogue containing acetate instead of chloroacetate groups, both having similar thermal destruction pathways. At the first heating steps, water is eliminated from Mo132Cl. Thermal destruction at higher temperature produces chloroacetamide, chloroacetonitrile, and other compounds.

Author keywords:

THERMAL-DECOMPOSITION; POLY(VINYL ALCOHOL); SALT FILMS; MO132

DOI:

10.1134/S0036023610080188

Web of Science ID:

ISI:000281332400018

Соавторы в МНС:

Другие поля

Поле	Значение
Month	AUG
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	THERMAL-DECOMPOSITION; POLY(VINYL ALCOHOL); SALT FILMS; MO132
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Tonkushina, Margarita/D-8463-2012
ORCID-Numbers	Tonkushina, Margarita/0000-0003-4371-3900
Funding-Acknowledgement	Russian Foundation for Basic Research {[}07-03-00362]; Federal Agency for Education; Federal Agency for Science and Innovations
Funding-Text	This work was supported by the Russian Foundation for Basic Research (project no. 07-03-00362), the Federal Agency for Education, and the Federal Agency for Science and Innovations.
Number-of-Cited-References	18
Usage-Count-Since-2013	8
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	643XA