Thermal Behavior of Polyoxometalate Mo132 / Ostroushko A. A.,Tonkushina M. O.,Safronov A. P.,Men'shikov S. Yu.,Korotaev V. Yu. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2009. - V. 54, l. 2. - P. 172-179.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

Thermal destruction of (NH(4))(42) {[}Mo(72)(VI)Mo(60)(V)O(372)(H(3)CCOO)(30)(H(2)O)(72)]30H(3)CCOONH(4)cen ter dot 250H(2)O, polyoxometalate Mo132, was analyzed. Differential scanning calorimetry (DSC) and mass spectrometry were investigative tools. Thermal destruction occurs in air and in nitrogen in three main stages. First, water is eliminated. The thermolysis products at higher temperatures include acetamide and acetonitrile. Molybdenum oxides are formed in solid products through an amorphous stage. The utility of NMR spectroscopy for analyzing poly(oxometalates) is demonstrated.

Author keywords:

THERMOCHEMICAL CHARGE GENERATION; POLYMER-SALT FILMS

DOI:

10.1134/S0036023609020028

Web of Science ID:

ISI:000265814300002

Соавторы в МНС:

Другие поля

Поле	Значение
Month	FEB
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	THERMOCHEMICAL CHARGE GENERATION; POLYMER-SALT FILMS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Korotaev, Vladislav/L-2692-2016 Tonkushina, Margarita/D-8463-2012
ORCID-Numbers	Korotaev, Vladislav/0000-0002-7492-5116 Tonkushina, Margarita/0000-0003-4371-3900
Funding-Acknowledgement	Russian Foundation for Basic Research {[}07-03-00362]
Funding-Text	This work was supported by the Russian Foundation for Basic Research (project no. 07-03-00362).
Number-of-Cited-References	19
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	13
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	442BH