Structure and properties of molybdate and tungstate complexes of polyvinyl alcohol / Ostroushko AA,Vilkova NV,Mogil'nikov UV // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2002. - V. 72, l. 1. - P. 1-8.

ISSN/EISSN:

1070-3632 / нет данных

Type:

Article

Abstract:

Photochemical reduction of ions of d metals (Mo and W) in the presence of polyvinyl alcohol depends on the acidity of the solutions and on the composition of the gas medium. The effect of UV radiation on the solubility of the components in the system polyvinyl alcohol-ammonium molybdate-water was studied. The mechanism of photochemical reactions and the structure of polymer-salt complexes were discussed. Mesomorphic formations similar to liquid-crystalline arise in the polymer-salt systems due to the rigidity induced in macromolecules of the water-soluble flexible-chain polymer by complex formation with inorganic polyions.

Author keywords:

нет данных

DOI:

10.1023/A:1015391721699

Web of Science ID:

ISI:000174763500001

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	JAN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Number-of-Cited-References	29
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	537NA