Synthesis and Kinetics of the Cyclization of 3-(Dialkylaminophenyl)-2-(phenylcarbonyl)-prop-2-enenitriles / Platonova A. Yu,Glukhareva T. V.,Zimovets O. A.,El'tsov O. S.,Morzherin Yu Yu // CHEMISTRY OF HETEROCYCLIC COMPOUNDS. - 2013. - V. 49, l. 5. - P. 736-745.

ISSN/EISSN:

0009-3122 / 1573-8353

Type:

Article

Abstract:

The reaction of ortho-(N,N-dialkylamino)benzaldehydes with benzoylacetonitrile gave fused 1,2,3,4-tetra-hydroquinolino-5-carbonitriles due to cyclization of the intermediate 2-(phenylcarbonyl)-3-{[}2-{[}(dialkyl-amino)phenyl]prop-2-enenitriles through a tert-amino effect mechanism. Kinetic studies were carried out on the cyclization of 2-(phenylcarbonyl)-3-{[}2-(piperidin-1-yl)phenyl]prop-2-enenitrile.

Author keywords:

N,N-dialkyl-o-vinylanilines; 1,2,3,4-tetrahydroquinolines; tert-amino effect; cyclization; reaction kinetics; stereoselectivity SPIRO DERIVATIVES; ACIDS

DOI:

10.1007/s10593-013-1305-2

Web of Science ID:

ISI:000323201200010

Соавторы в МНС:

Другие поля

Поле	Значение
Month	AUG
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
EISSN	1573-8353
Keywords-Plus	SPIRO DERIVATIVES; ACIDS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	alena-platonova@mail.ru
ResearcherID-Numbers	Morzherin, Yury/M-7420-2013 Glukhareva, Tatiana/A-4610-2016
ORCID-Numbers	Morzherin, Yury/0000-0002-1333-6676 Glukhareva, Tatiana/0000-0002-5231-9879
Number-of-Cited-References	16
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	20
Journal-ISO	Chem. Heterocycl. Compds.
Doc-Delivery-Number	202GD