Stereoselective synthesis of spiro derivatives of 2,4-dimethyl-2,3,4,4a,5,6-hexahydro-6H-benzo{[}c]quinolizine / Deeva EV,Glukhareva TV,Zybina NA,Morzherin YY // RUSSIAN CHEMICAL BULLETIN. - 2005. - V. 54, l. 6. - P. 1537-1538.

ISSN/EISSN:

1066-5285 / 1573-9171

Type:

Article

Abstract:

The reactions of 2-(3,5-dimethylpiperidino)benzaldehyde with Meldrum's acid and cyclo-hexane-1,3-dione occur as a tandem of the Knoevenagel condensation and cyclization promoted by the tert-amino effect. The cyclization yields only one isomer with the axial hydrogen atoms in positions 4 and 4a of the benzoquinolizine ring.

Author keywords:

tert-amino effect; cyclization; nitrogen-containing heterocycles; spiroheterocycles

DOI:

10.1007/s11172-005-0444-8

Web of Science ID:

ISI:000234157200034

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
EISSN	1573-9171
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	morjerine@htf.ustu.ru
ResearcherID-Numbers	Morzherin, Yury/M-7420-2013 Glukhareva, Tatiana/A-4610-2016
ORCID-Numbers	Morzherin, Yury/0000-0002-1333-6676 Glukhareva, Tatiana/0000-0002-5231-9879
Number-of-Cited-References	7
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	996EM