2-amino-5-aryl- and 2-amino-5-hetaryl-3-cyano-6-(2-thienyl)pyridines as Organic Dyes for Dye-Sensitized Solar Cells: Synthesis, Quantum-Chemical Calculations, Spectral and Electrochemical Properties / Verbitskiy E. V.,Slepukhin P. A.,Subbotina Yu. O.,Valova M. S.,Schepochkin A. V.,Cheprakova E. M.,Rusinov G. L.,Charushin V. N. // CHEMISTRY OF HETEROCYCLIC COMPOUNDS. - 2014. - V. 50, l. 6. - P. 814-827.

ISSN/EISSN:

0009-3122 / 1573-8353

Type:

Article

Abstract:

Novel organic dyes containing pyridine ring as the anchoring group with carbazole or triphenylamine substituents were synthesized from available 4-(2-thienyl)pyrimidine using the Kost-Sagitullin rearrangement and Suzuki cross coupling assisted by microwave irradiation. The photophysical (absorption and photoluminescence spectra) and electrochemical properties of these compounds were investigated. The data from quantum calculations show that all of the dyes are potentially good photosensitizers for dye-sensitized solar cells.

Author keywords:

dyes; pyridines; pyrimidines; dye-sensitized solar cells WITHDRAWING ANCHORING GROUP; 2 PYRIDYL GROUPS; FLUORESCENT DYES; TD-DFT; RING

DOI:

10.1007/s10593-014-1536-x

Web of Science ID:

ISI:000340878300004

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
EISSN	1573-8353
Keywords-Plus	WITHDRAWING ANCHORING GROUP; 2 PYRIDYL GROUPS; FLUORESCENT DYES; TD-DFT; RING
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	verbitsky@ios.uran.ru
Funding-Acknowledgement	Ural Branch of the Russian Academy of Sciences {[}12-P-3-1014, 12-T-3-1025, 12-T-3-1031]; Russian Foundation for Basic Research {[}13-03-96049-p\_ural\_a, 13-03-12434 ofi\_m2, 13-03-90606-Arma, 14-03-31040-mol\_a]; Grants Council of the President of the Russian Federation {[}MK-3939.2014.3]; Sverdlovsk Oblast Government
Funding-Text	This work was carried out in the Programs of the Ural Branch of the Russian Academy of Sciences 12-P-3-1014, 12-T-3-1025, 12-T-3-1031, Russian Foundation for Basic Research grants 13-03-96049-p\_ural\_a, 13-03-12434 ofi\_m2, 13-03-90606-Arma, and 14-03-31040-mol\_a and with the support of the Grants Council of the President of the Russian Federation (grant MK-3939.2014.3) and the Sverdlovsk Oblast Government.
Number-of-Cited-References	21
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	24
Journal-ISO	Chem. Heterocycl. Compds.
Doc-Delivery-Number	AN8TV