From 1,2,4-triazines towards substituted pyridines and their cyclometallated Pt complexes / Kozhevnikov Valery N.,Ustinova Maria M.,Slepukhin Pavel A.,Santoro Amedeo,Bruce Duncan W.,Kozhevnikov Dmitry N. // TETRAHEDRON LETTERS. - 2008. - V. 49, l. 26. - P. 4096-4098.

ISSN/EISSN:

0040-4039 / нет данных

Type:

Article

Abstract:

A new, efficient methodology for the synthesis of substituted thienylpyridines includes the synthesis of 3-thienyl-1,2,4-triazines using simple heterocyclisation followed by easy transformation of the triazine ring to a pyridine through an aza Diels-Alder approach. A variety of substituted pyridines can be easily achieved using cheap, commercially available reagents such as bromoacetylarenes, aroyl hydrazides, norbornadiene, and enamines in various combinations. New thienylpyridines form phosphorescent cyclometallated Pt complexes. (C) 2008 Published by Elsevier Ltd.

Author keywords:

thienylpyridines; 1,2,4-triazines; cyclometallated Pt complexes DIIMINE COMPLEXES; DIELS-ALDER; PLATINUM

DOI:

10.1016/j.tetlet.2008.04.138

Web of Science ID:

ISI:000256771400003

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	JUN 23
Publisher	PERGAMON-ELSEVIER SCIENCE LTD
Address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language	English
Keywords-Plus	DIIMINE COMPLEXES; DIELS-ALDER; PLATINUM
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	dnk@ios.uran.ru
ResearcherID-Numbers	Kozhevnikov, Valery/B-1178-2010
ORCID-Numbers	Kozhevnikov, Valery/0000-0001-7032-8886 Bruce, Duncan/0000-0002-1365-2222
Number-of-Cited-References	21
Usage-Count-Since-2013	6
Journal-ISO	Tetrahedron Lett.
Doc-Delivery-Number	313WT