Spectroelectrochemical study of neptunium in molten LiCl-KCl eutectic / Polovov Ilya B.,Sharrad Clint A.,May Lain,Volkovich Vladimir A.,Vasin Boris D. // ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES. - 2007. - V. 62, l. 12. - P. 745-748.

ISSN/EISSN:

0932-0784 / нет данных

Type:

Article

Abstract:

Neptunium behaviour in an LiCl-KCl eutectic melt at 723 K was studied using spectroelectrochemistry. Cathodic reduction of neptunium(IV)-containing melts led to the formation of Np(III) ions and then neptunium metal. Electronic absorption spectra of Np(IV) and Np(III) chloro species in LiCl-KCl melt were recorded and resolved into individual Gaussian bands. The nature of neptunium complex ions in the melt is discussed.

Author keywords:

neptunium; chloride melts; spectroscopy; electrochemistry; spectroelectrochemistry

DOI:

нет данных

Web of Science ID:

ISI:000252711600012

Соавторы в МНС:

Другие поля

Поле	Значение
Month	DEC
Publisher	VERLAG Z NATURFORSCH
Address	POSTFACH 2645, 72016 TUBINGEN, GERMANY
Language	English
Research-Areas	Chemistry; Physics
Web-of-Science-Categories	Chemistry, Physical; Physics, Multidisciplinary
Author-Email	polovov@dpt.ustu.ru
ResearcherID-Numbers	Volkovich, Vladimir/K-8339-2012 Sharrad, Clint/E-2499-2017
ORCID-Numbers	Volkovich, Vladimir/0000-0003-4438-1194 Sharrad, Clint/0000-0001-7372-8666
Number-of-Cited-References	6
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	7
Journal-ISO	Z. Naturfors. Sect. A-J. Phys. Sci.
Doc-Delivery-Number	256EX