Formation of the O-2-solid electrolyte during the interaction of Bi2O3 with WO3 / Neiman AY,Kirpishchikova TA // RUSSIAN JOURNAL OF ELECTROCHEMISTRY. - 1996. - V. 32, l. 4. - P. 471-477.

ISSN/EISSN:

1023-1935 / нет данных

Type:

Article

Abstract:

Electrochemical techniques are applied to the reaction between Bi2O3 and WO3 who se products are the O2--solid electrolytes. At polarizations from -1.0 to 1.0 V and current densities from -50 to 10 mA/cm(2), the reaction rate is constant and the reaction potential difference is close to zero. Both these results are consistent with those predicted by the theory of the O2--conductors. The new model suggested maintains that the paths of charge and mass transport coincide during the synthesis of poorly conducting molybdates and tungstates. This leads to the exaltation of the limiting mass flow by the charge flow and to anomalous behavior of the reactions. During the synthesis of electrolytic phases, the charge transport in the bulk does not affect the mass transport over the surface.

Author keywords:

нет данных

DOI:

нет данных

Web of Science ID:

ISI:A1996UK53200012

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	APR
Publisher	INTERPERIODICA
Address	PO BOX 1831, BIRMINGHAM, AL 35201-1831
Language	English
Research-Areas	Electrochemistry
Web-of-Science-Categories	Electrochemistry
Number-of-Cited-References	18
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Electrochem.
Doc-Delivery-Number	UK532