Synthesis of films of solid solutions Cd (x) Pb1-x S by the method of ion-exchange substitution / Maskaeva L. N.,Forostyanaya N. A.,Markov V. F.,Voronin V. I. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2015. - V. 60, l. 5. - P. 552-559.

ISSN/EISSN:

0036-0236 / 1531-8613

Type:

Article

Abstract:

The possibility of obtaining films of substitutional solid solutions in a sulfide system via ionic exchange at the interface between the CdS film and the aqueous solution of a lead salt has been shown. The composition, structure, and morphology of freshly deposited films of CdS, PbS, and CdS layers held for 60-540 min at 353-368 K in an aqueous solution of lead acetate have been studied. It has been established by the methods of Raman spectroscopy (RS) and glancing-angle X-ray diffraction (GAXRD) that, due to ion-exchange processes, the formation of supersaturated substitutional solid solutions Cd (x) Pb1 - x S (x a parts per thousand currency sign 0.31) occurs in the film, the cadmium content in which decreases gradually over the film thickness.

Author keywords:

RAMAN-SPECTROSCOPY; THIN-FILMS; PBS

DOI:

10.1134/S0036023615050150

Web of Science ID:

ISI:000355150900003

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAY
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1531-8613
Keywords-Plus	RAMAN-SPECTROSCOPY; THIN-FILMS; PBS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Author-Email	mln@ural.ru
ResearcherID-Numbers	Voronin, Vladimir/J-7733-2013
ORCID-Numbers	Voronin, Vladimir/0000-0002-3901-9812
Funding-Acknowledgement	Ministry of Education and Science of Russia {[}4.1270.2014/K]; Government of the Russian Federation {[}211, 02.A03.21.0006]; URFU
Funding-Text	This study was supported by the Ministry of Education and Science of Russia in the frame of fulfillment of the Governmental Assignment No. 4.1270.2014/K.; This work was supported by the program no. 211 of the Government of the Russian Federation (project no. 02.A03.21.0006); and by the URFU program for supporting young scientists within the framework of the realization of the program of development of the UrFU.
Number-of-Cited-References	17
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	4
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	CJ0FJ