The effect of cadmium salts on the composition and properties of hydrochemically precipitated CdxPb1-xS solid solution / Maskaeva LN,Markov VF,Gusev AI // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2004. - V. 49, l. 7. - P. 971-977.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

Films of CdxPb1-xS supersaturated substitutional solid solution (ss) were prepared hydrochemically at 353 K from citrate-ammoniac batches that contained various cadmium salts (CdSO4, Cd(NO3)(2), Cd(CH3COO)(2), CdCl2, CdBr2, CdI2). The anionic component of the cadmium salt was found to affect the solid-solution composition. In the order of the decreasing CdS concentrations in the sol id solution, the cadmium salts are arranged as follows: CdSO4 --> Cd(NO3)(2) --> Cd(CH3COO)(2) --> CdCl2 --> CdBr2 --> CdI2. The structure, chemical and phase compositions, morphology, and spectroscopic parameters of the films were studied. A mechanism was advanced to interpret the effect of the cadmium salt anion on the solid-solution formation.

Author keywords:

FILMS; GROWTH

DOI:

нет данных

Web of Science ID:

ISI:000223518300002

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUL
Publisher	INTERPERIODICA
Address	PO BOX 1831, BIRMINGHAM, AL 35201-1831 USA
Language	English
Keywords-Plus	FILMS; GROWTH
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Number-of-Cited-References	26
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	849DG