Theory of structural transformations in ferrofluids: Chains and ``gas-liquid{''} phase transitions / Zubarev AY,Iskakova LY // PHYSICAL REVIEW E. - 2002. - V. 65, l. 6, 1.

ISSN/EISSN:

2470-0045 / 2470-0053

Type:

Article

Abstract:

We consider a ferrofluid consisting of identical spherical particles with a permanent magnetic moment. Under the assumption that linear flexible chains can appear in the ferrofluid, we estimate the distribution function of the number of particles inside the chain. The analysis is done and simple expressions for the size distribution function are obtained in asymptotics of a strong magnetic interaction between the particles inside one chain. We studied the influence of the linear chains on conditions and scenarios of bulk ``gas-liquid{''} phase transition in the ensemble of the particles under an infinitely strong magnetic field. In order to study the influence of the chains on bulk ``gas-liquid{''} phase transition in the ensemble of the particles, their chemical potential mu is calculated in the model of separate interacting particles as well as in the model with chains, taking into account the interaction between them. When the temperature is low enough, van der Waals loops appear on the plots of mu versus volume concentration Phi of the particles in the first model; function mu(Phi) increases monotonically in the second model for all examined temperatures. This means that the condensation ``gas-liquid{''} phase transition can take place in the model of individual particles; however, formation of the chains in real ferrofluids prevents the appearance of this transition.

Author keywords:

DIPOLAR HARD-SPHERES; EXTERNAL MAGNETIC-FIELD; FLUIDS; ASSOCIATION; AGGLOMERATION; COEXISTENCE; PARTICLES; KINETICS; COLLOIDS; RODS

DOI:

10.1103/PhysRevE.65.061406

Web of Science ID:

ISI:000176762500032

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	AMER PHYSICAL SOC
Address	ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA
Language	English
Article-Number	061406
EISSN	2470-0053
Keywords-Plus	DIPOLAR HARD-SPHERES; EXTERNAL MAGNETIC-FIELD; FLUIDS; ASSOCIATION; AGGLOMERATION; COEXISTENCE; PARTICLES; KINETICS; COLLOIDS; RODS
Research-Areas	Physics
Web-of-Science-Categories	Physics, Fluids \& Plasmas; Physics, Mathematical
Author-Email	Andrey.Zubarev@usu.ru
ResearcherID-Numbers	Zubarev, Adrey/B-4752-2014
Number-of-Cited-References	34
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	8
Journal-ISO	Phys. Rev. E
Doc-Delivery-Number	572FH