Electrochemical Properties of Molybdenum in Alkali Chloride Melts / Ivanov A. B.,Volkovich V. A.,Likhachev P. Yu.,Kamalov R. V. // . - 2014. - V. 64, l. 4. - P. 377-387.

ISSN/EISSN:
1938-5862 / нет данных
Type:
Proceedings Paper
Abstract:
Behavior of molybdenum was studied in individual fused alkali chlorides and their mixtures employing electrochemical and spectroscopic techniques. Formal standard electrode potentials of molybdenum and thermodynamics of molybdenum chloride were obtained in molten LiCl, NaCl, KCl, RbCl, CsCl at 1123 K, NaCl-CsCl eutectic at 793-1023 K, NaCl-KCl equimolar mixture at 973-1123 K, LiCl-KCl-CsCl eutectic at 633-1173 K. Diffusion coefficients of molybdenum ions were determined in LiCl-KCl-CsCl eutectic melt. Electronic absorption spectra of Mo(III) ions were measured in individual salts and their mixtures and spectroscopic parameters of MoCl63- complex ions determined.
Author keywords:
SPECTROSCOPY
DOI:
10.1149/06404.0377ecst
Web of Science ID:
ISI:000356725500042
Соавторы в МНС:
Другие поля
Поле Значение
Editor Reichert, WM and Ispas, A and Bund, A and DeLong, HC and Haverhals, LM and Mizuhata, M and Trulove, PC and Mantz, RA
Booktitle MOLTEN SALTS AND IONIC LIQUIDS 19
Series ECS Transactions
Note 19th Int Symposium on Molten Salts and Ion Liquids as part of the Joint Meeting of the 226th Meeting of the Electrochem Soc, the XXIX Congreso de la Sociedad Mexicana de Electroquinica / 7th Meeting of the Mexico Sect of the Electrochem Soc, Cancun, MEXICO, OCT 05-09, 2014
Organization Electrochem Soc Phys \& Analyt Electrochemistry Div; Electrochem Soc Energy Technol Div; Electrochem Soc Electrodeposit Div
Publisher ELECTROCHEMICAL SOC INC
Address 65 S MAIN ST, PENNINGTON, NJ 08534-2839 USA
Language English
ISBN 978-1-60768-541-8
Keywords-Plus SPECTROSCOPY
Research-Areas Electrochemistry; Energy \& Fuels; Metallurgy \& Metallurgical Engineering
Web-of-Science-Categories Electrochemistry; Energy \& Fuels; Metallurgy \& Metallurgical Engineering
ResearcherID-Numbers Volkovich, Vladimir/K-8339-2012 Kamalov, Robert/E-1097-2014 Ivanov, Alexander/F-7655-2017
ORCID-Numbers Volkovich, Vladimir/0000-0003-4438-1194 Kamalov, Robert/0000-0001-6034-2844
Number-of-Cited-References 22
Usage-Count-Last-180-days 1
Usage-Count-Since-2013 8
Doc-Delivery-Number BC9PF