Reaction of Curium(III) Ions with Oxo-species in Alkali Chloride Melts / Osipenko A. G.,Maershin A. A.,Volkovich V. A.,Kormilitsyn M. V.,Bychkov A. V. // . - 2010. - V. 33, l. 7. - P. 401-408.

ISSN/EISSN:

1938-5862 / нет данных

Type:

Proceedings Paper

Abstract:

Electronic absorption spectra of curium(III) chloro-species were measured in 3LiCl-2KCl (at 450 degrees C) and NaCl-2CsCl (at 550, 650 and 750 degrees C) eutectic melts and the molar absorption coefficients determined. The effect of oxide species addition to the melt on the absorption spectra of curium was studied. A new species, evident from the absorption bands around 360 nm, is formed when barium oxide is dissolved in the melt or O-2-Cl-2 or Ar-HCl-H2O gas mixtures bubbled through. This species is ascribed to soluble curium oxychloride. It does not react with chlorine bubbled through the melt unless there is carbon present.

Author keywords:

SPECTRA

DOI:

10.1149/1.3484798

Web of Science ID:

ISI:000313618000042

Соавторы в МНС:

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Другие поля

Поле	Значение
Editor	Fox, DM and Mizuhata, M and DeLong, HC and Mantz, RA and Trulove, PC
Booktitle	MOLTEN SALTS AND IONIC LIQUIDS 17
Series	ECS Transactions
Note	17th International Symposium on Molten Salts and Ionic Liquids as Part of the 218th Meeting of the Electrochemical-Society, Las Vegas, NV, OCT 10-15, 2010
Organization	Electrochem Soc (ECS); Phys \& Analyt Electrochem (PAED); Electrodeposit; Energy Technol (ETD)
Publisher	ELECTROCHEMICAL SOC INC
Address	65 S MAIN ST, PENNINGTON, NJ 08534-2839 USA
Language	English
ISBN	978-1-60768-176-2
Keywords-Plus	SPECTRA
Research-Areas	Electrochemistry
Web-of-Science-Categories	Electrochemistry
ResearcherID-Numbers	Volkovich, Vladimir/K-8339-2012
ORCID-Numbers	Volkovich, Vladimir/0000-0003-4438-1194
Number-of-Cited-References	15
Doc-Delivery-Number	BDK82