Nano materials from molten salts: Preparation of nano-sized lanthanide phosphates from chloride melts / Volkovich VA,Griffiths TR,Thied RC // . - 2002. - V. 2002, l. 19. - P. 590-602.

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Type:

Proceedings Paper

Abstract:

The formation of phosphates of the lighter lanthanides (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb and Dy) by reactions with alkali metal phosphates in a LiCl-KCl eutectic melt between 450 and 650 T and in a NaCl-KCl equimolar melt at 750 degreesC has been studied under an argon atmosphere. Ortho-, meta- and pyrophosphate precursors have been employed. The reaction results in the formation of single lanthanide or double alkali metal-lanthanide orthophosphates. The mean crystallite size of precipitated phosphates was evaluated from X-ray powder diffraction patterns, and found to be within 300 - 450 (A) over circle. The effects of temperature, melt composition and the nature of phosphate precursor on the products formed were investigated.

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DOI:

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Web of Science ID:

ISI:000180660100057

Соавторы в МНС:

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Другие поля

Поле	Значение
Editor	Trulove, PC and DeLong, HC and Mantz, RA and Stafford, GR and Matsunaga, M
Booktitle	MOLTEN SALTS XIII
Series	ELECTROCHEMICAL SOCIETY SERIES
Note	13th International Symposium on Molten Salts, PHILADELPHIA, PA, MAY 12-17, 2002
Organization	Electrochem Soc, Phys Electrochem Div; Electrochem Soc, High Temp Mat Div; Electrochem Soc, Electrodeposit Div
Publisher	ELECTROCHEMICAL SOCIETY INC
Address	65 S MAIN ST, PENNINGTON, NJ 08534-2839 USA
Language	English
ISBN	1-56677-343-1
Research-Areas	Thermodynamics; Electrochemistry; Instruments \& Instrumentation
Web-of-Science-Categories	Thermodynamics; Electrochemistry; Instruments \& Instrumentation
ResearcherID-Numbers	Volkovich, Vladimir/K-8339-2012
ORCID-Numbers	Volkovich, Vladimir/0000-0003-4438-1194
Number-of-Cited-References	10
Doc-Delivery-Number	BW02C