Complexes of Mono- and Bis(2-carboxyethyl)-2-picolylamine: Synthesis and Crystal and Molecular Structures / Pestov A. V.,Permyakov A. E.,Slepukhin P. A.,Neudachina L. K.,Yatluk Yu. G. // RUSSIAN JOURNAL OF COORDINATION CHEMISTRY. - 2010. - V. 36, l. 10. - P. 769-777.

ISSN/EISSN:

1070-3284 / нет данных

Type:

Article

Abstract:

N-(2-Pyridylmethyl)iminodipropionic (I) and N-(2-pyridylmethyl)-3-aminopropionic acids (II) were obtained. A reaction of acid I with a Cu(II) salt gave a 2: 2 complex (III); a reaction of acid II with a Ni(II) salt yielded a 1 : 2 complex (IV). The crystal structures of these complexes were determined by X-ray diffraction. The abilities of compounds I and II to form complexes were compared with the literature data for other ligands containing the N-(2-pyridylmethyl)amino fragment. The structural features of the chelate complexes with 2-aminomethylpyridine derivatives were revealed, depending on the other substituents and the metal center.

Author keywords:

COPPER(II) COMPLEXES; MAGNETIC-PROPERTIES; LIGAND; COORDINATION; DESIGN; MODELS

DOI:

10.1134/S1070328410100088

Web of Science ID:

ISI:000283151900008

Соавторы в МНС:

Другие поля

Поле	Значение
Month	OCT
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	COPPER(II) COMPLEXES; MAGNETIC-PROPERTIES; LIGAND; COORDINATION; DESIGN; MODELS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Author-Email	yatluk@ios.uran.ru
Funding-Acknowledgement	Federal Agency for Education {[}P 278]
Funding-Text	This work was supported by the Federal Agency for Education (Federal Target Program ``Scientific and Pedagogical Personnel of an Innovative Russia{''} for 2009-2013, State Contract no. P 278, July 23, 2009).
Number-of-Cited-References	26
Usage-Count-Since-2013	7
Journal-ISO	Russ. J. Coord. Chem.
Doc-Delivery-Number	666WA