Synthesis, Structure, and Properties of M3VO2(SO4)(2) (M = Rb, Cs) / Krasil'nikov V. N.,Tyutyunnik A. P.,Zubkov V. G.,Berger I. F.,Perelyaeva L. A.,Baklanova I. V. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2010. - V. 55, l. 9. - P. 1331-1338.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

Vanadium(V) complexes of general composition M3VO2(SO4)(2) (M = Rb, Cs) were synthesized by a solid-state route. The individuality of the synthesized compounds was proved by X-ray and neutron diffraction, vibrational spectroscopy, and microscopic analysis. The X-ray diffraction patterns of M3VO2(SO4)(2) were indexed to fit the monoclinic system (space group P2/c, Z = 4) with the following unit cell parameters: a = 11.6487(2) angstrom, b = 8.4469(2) angstrom, c = 12.1110(2) angstrom, beta = 109.483(1)degrees, V = 1123.43 angstrom(3) (Rb); a = 12.0546(3) angstrom, b = 8.7706(2) angstrom, c = 12.6496(3) angstrom, beta = 109.843(2)degrees, V = 1257.99 angstrom(3) (Cs). In the crystal structure of M3VO2(SO4)(2), {[}VO2(SO4)(2)](3-) complex anions can be discerned in which the vanadium atom is surrounded by five oxygen atoms: two oxygen atoms form short terminal V-O bonds, and three oxygen atoms are from the two sulfato groups, one of which acts as a monodentate ligand and the other acts as a bidentate chelating ligand.

Author keywords:

CRYSTAL-STRUCTURE; SPECTROSCOPIC PROPERTIES; CATALYSTS

DOI:

10.1134/S0036023610090019

Web of Science ID:

ISI:000283092800001

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	CRYSTAL-STRUCTURE; SPECTROSCOPIC PROPERTIES; CATALYSTS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Tyutyunnik, Alexander/P-2230-2015
Number-of-Cited-References	26
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	3
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	666DT