Synthesis, structure, and properties of V2O3(XO4)(2) (X = S, Se) / Tyutyunnik A. P.,Krasil'nikov V. N.,Zubkov V. G.,Perelyaeva L. A.,Baklanova I. V. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2010. - V. 55, l. 4. - P. 501-507.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

Compounds described as V2O3(XO4)(2), where X = S or Se, were prepared from vanadium(V) oxide mixtures with concentrated sulfuric and selenic acids. The physicochemical properties of the products were studied; for V2O3(SeO4)(2), the crystal structure was determined by powder X-ray diffraction and neutron diffraction, and its key differences from the structure of V2O3(SO4)(2) were identified. V2O3(SeO4)(2) crystallizes in the monoclinic system with the unit cell parameters a = 15.3831(2), b = 5.54096(5), c = 9.71644(7), beta = 111.886(1)A degrees, V = 768.51(3), space group C2/c (no. 15).

Author keywords:

SPECTRA

DOI:

10.1134/S0036023610040042

Web of Science ID:

ISI:000277345800004

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	APR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	SPECTRA
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Tyutyunnik, Alexander/P-2230-2015
Funding-Acknowledgement	Presidential Grant for Support of Leading Scientific Schools {[}Nsh-1170.2008.3]
Funding-Text	This work was supported by a Presidential Grant for Support of Leading Scientific Schools (Nsh-1170.2008.3).
Number-of-Cited-References	14
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	6
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	592AD