Crystal structure and spectroscopic properties of A{[}VO2(SO4)(H2O)(2)] center dot H2O (A = k, rb, tl, NH4) compounds / Zubkov V. G.,Tyutyunnik A. P.,Berger I. F.,Krasil'nikov V. N.,Perelyaeva L. A.,Baklanova I. V. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2007. - V. 52, l. 9. - P. 1415-1423.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

The crystal structure of dioxovanadium(V) sulfate trihydrates A{[}VO2(SO4)(H2O)(2)] center dot H2O, where A is K, Rb, Tl, or NH4, has been determined based on a combination of neutron and X-ray diffraction data. The compounds are isostructural and have a monoclinic lattice (space group P2(1), Z = 2) with unit cell parameters a = 6.24535(8), 6.26016(7), 6.25817(5), and 6.2500(1) angstrom; b = 9.8417(1), 9.99736(8), 9.96217(9), and 9.9742(1) angstrom; c = 6.52113(8), 6.69303(5), 6.70379(6), and 6.70334(9) angstrom; beta = 106.99(1)degrees, 107.83(1)degrees, and 107.83(1)degrees, 107.99(1)degrees, respectively. The SO4 tetrahedra and VO4(H2O)(2) octahedra share an oxygen vertex to form infinite isolated chains. Atoms A have CN = 10. IR and Raman spectroscopy data are reported.

Author keywords:

SYSTEM

DOI:

10.1134/S0036023607090173

Web of Science ID:

ISI:000249630600017

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	SYSTEM
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Tyutyunnik, Alexander/P-2230-2015
Number-of-Cited-References	18
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	4
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	212XP