Vibrational spectra of cyanoferrate(II) and cyanoferrate(III) complexes of tin and lead / Denisova IA,Maksimova LG,Kovyazina SA,Polyakov EV,Zainullina VM,Zhuravlev NA,Zubkov VG,Tyutyunnik AP,Koryakova OV // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2004. - V. 49, l. 9. - P. 1414-1420.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

The IR and Raman spectra of crystal hydrates and anhydrous phases of p-element (tin, lead) cyanoferrate(II) and cyanoferrate(III) complexes are systematically investigated. Tendencies of the evolution of the vibrational stretching frequencies v(CdropN), v(Fe-C), and v(OH) are determined as functions of the composition, structural type of the compound, the existence of molecular water in the crystal lattice of the cyanoferrate (CF), the main bond strength, the outer-sphere cation radius, and the iron oxidation number. The vibrational spectra are matched to the overlap population parameters of the Sn(Pb)-N and Fe-C crystal orbitals derived from quantum-chemical zone calculations.

Author keywords:

CRYSTAL-STRUCTURE; INFRARED SPECTRA; FERROCYANIDE; ION; CO

DOI:

нет данных

Web of Science ID:

ISI:000224291700019

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	SEP
Publisher	INTERPERIODICA
Address	PO BOX 1831, BIRMINGHAM, AL 35201-1831 USA
Language	English
Keywords-Plus	CRYSTAL-STRUCTURE; INFRARED SPECTRA; FERROCYANIDE; ION; CO
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Polyakov, Evgeny/A-7817-2012 Tyutyunnik, Alexander/P-2230-2015
Number-of-Cited-References	32
Usage-Count-Since-2013	3
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	859TV