Synthesis and crystal structure of LiMg4(VO4)(3) / Tyutyunnik AP,Zubkov VG,Surat LL,Slobodin BV // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2004. - V. 49, l. 4. - P. 553-559.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

A new compound LiMg4(VO4)(3) is synthesized using solid-phase synthesis, and its crystal structure is studied by the Rietveld full-profile analysis method (QSAS). The tetragonal (space group I (4) over bar 2d, Z = 4) unit cell parameters are a = 6.86707(2) Angstrom and c = 18.9545(1) Angstrom. The LiMg4(VO4)(3) lattice consists of helices of edgesharing MgO6 octahedra. The VO4 tetrahedra connect the helices to form a three-dimensional framework. The lithium atom is located in the center of a distorted tetragonal prism with the nonequivalent Li-O distances 2.716(3) x 4 and 2.267(5) x 4 Angstrom. This compound is isostructural with NaMg4(VO4)(3).

Author keywords:

RELIABILITY; REFINEMENT; CRITERION; PHASE

DOI:

нет данных

Web of Science ID:

ISI:000221187800010

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	APR
Publisher	INTERPERIODICA
Address	PO BOX 1831, BIRMINGHAM, AL 35201-1831 USA
Language	English
Keywords-Plus	RELIABILITY; REFINEMENT; CRITERION; PHASE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Tyutyunnik, Alexander/P-2230-2015
Number-of-Cited-References	11
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	2
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	817OW