Synthesis, crystal structure, and magnetic properties of quasi-one-dimensional oxides Ca3Co1+xMn1-xO6 / Bazuev GV,Zubkov VG,Berger IF,Krasil'nikov VN // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2001. - V. 46, l. 3. - P. 317-322.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

Synthetic conditions and magnetic properties of quasi-one-dimensional mixed oxides Ca3Co1 + xMn1 - xO6 were investigated for x = 0, 0.25, and 1.0 (K4CdCl6 structure type, space group R(3) over barc, Z = 6). The crystal structure of Ca3CoMnO6 was refined using neutron diffraction analysis. The Co-O (2.140 Angstrom) and Mn-O (1.906 Angstrom) bond lengths give evidence that the 3d elements in this compound exist in the form of the Co2+ and Mn4+ cations. In contrast to the Ca3Co2O6 ferromagnet (T-K = 24 K), the manganese-containing phases are characterized by antiferromagnet interactions with the Neel temperatures of 18 K (x = 0.25) and 13 K (x = 0).

Author keywords:

CA3CO2O6

DOI:

нет данных

Web of Science ID:

ISI:000167513800001

Соавторы в МНС:

—

Другие поля

Поле	Значение
Month	MAR
Publisher	INTERPERIODICA
Address	PO BOX 1831, BIRMINGHAM, AL 35201-1831 USA
Language	English
Keywords-Plus	CA3CO2O6
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Number-of-Cited-References	15
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	411RV