Anhydrous tin and lead hexacyanoferrates (II). Part I. Synthesis and crystal structure. / Zubkov VG,Tyutyunnik AP,Berger IF,Maksimova LG,Denisova TA,Polyakov EV,Kaplan IG,Voronin VI // SOLID STATE SCIENCES. - 2001. - V. 3, l. 3. - P. 361-367.

ISSN/EISSN:

1293-2558 / нет данных

Type:

Article

Abstract:

The crystal structure of Pb2Fe(CN)(6) and Sn2Fe(CN)(6) has been first determined and refined using the Rietveld method with combined Cu-K alpha (1) X-ray and constant-wavelength neutron powder diffraction data in space group P-3 (147, Z = 1). The unit cell constants are a = 7.1346(1) and 7.1805(1) Angstrom, c = 5.4531(2) and 5.3639(1) Angstrom, respectively. The compounds are layered, groups of three nearest {[}Fe(CN)(6)](4-)-complexes are joined to layers by means of Pb or Sn atoms. The same Pb or Sn atoms (c.n. = 3+3) joint three nearest complexes from the next layer. The jointing goes through `nitrogen-lead(tin)-nitrogen' bonds. (C) 2001 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

Author keywords:

anhydrous tin; hexacyanoferrates (II); Pb2Fe(CN)(6)

DOI:

10.1016/S1293-2558(00)01103-1

Web of Science ID:

ISI:000168323500014

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	MAR-APR
Publisher	EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
Address	23 RUE LINOIS, 75724 PARIS CEDEX 15, FRANCE
Language	English
Research-Areas	Chemistry; Physics
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Physical; Physics, Condensed Matter
ResearcherID-Numbers	Polyakov, Evgeny/A-7817-2012 Tyutyunnik, Alexander/P-2230-2015 Voronin, Vladimir/J-7733-2013
ORCID-Numbers	Voronin, Vladimir/0000-0002-3901-9812
Number-of-Cited-References	14
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	8
Journal-ISO	Solid State Sci.
Doc-Delivery-Number	425ZA