Crystal structure and magnetic properties of one-dimensional oxides Ca(3)AMnO(6) (A = Zn, Ni) / Bazuev GV,Zubkov VG,Berger IF,Arbuzova TI // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2000. - V. 45, l. 7. - P. 1091-1097.

ISSN/EISSN:

0036-0236 / нет данных

Type:

Article

Abstract:

The structure of the one-dimensional complex oxide Ca3NiMnO6 (the structural type of K4CdCl6, space group R(3)over barc, Z = 6) was refined by X-ray and neutron diffraction. For this compound and its zinc analogue, magnetic susceptibility chi and magnetization were measured. The interatomic distances in oxygen polyhedra were calculated. The Ni-O and Mn-O bond lengths (2.137 and 1.905 Angstrom, respectively) permit the conclusion that the 3d metals in this phase occur as the cations Ni2+ and Mn4+. Ca3ZnMnO6 is isostructural with Ca3NiMnO6 and has similar unit cell dimensions. Both compounds are antiferromagnets with low Neel temperatures.

Author keywords:

нет данных

DOI:

нет данных

Web of Science ID:

ISI:000089007700021

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	JUL
Publisher	INTERPERIODICA
Address	PO BOX 1831, BIRMINGHAM, AL 35201-1831 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Arbuzova, Tamara/K-1702-2013
ORCID-Numbers	Arbuzova, Tamara/0000-0003-0360-2210
Number-of-Cited-References	11
Usage-Count-Last-180-days	3
Usage-Count-Since-2013	5
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	348VT