Synthesis and properties of Pb1-xVxO2-x(OH)(x) solid solutions / Volkov VL,Zakharova GS,Kuznetsov MV,Zubkov VG,Berger IF,Tyutyunnik AP // INORGANIC MATERIALS. - 2000. - V. 36, l. 1. - P. 49-53.

ISSN/EISSN:

0020-1685 / нет данных

Type:

Article

Abstract:

Pb1-xVxO2-x(OH)(x) (0 < x less than or equal to 0.30) solid solutions with the rutile structure were prepared by reacting humid beta-PbO2 + V2O5 mixtures at temperatures from 200 to 250 degrees C. At higher vanadium contents, lead hexavanadate, PbV6O16, was formed, as inferred from IR spectroscopy data. The structural and electrical properties of the solid solutions were studied, and the valence state of the constituent ions was determined. All of the vanadium has a valence of 4+ for x less than or equal to 0.06and 5+ for x > 0.15. The lead ions are in the oxidation states 4+ and 2+ over the entire range of solid solution.

Author keywords:

нет данных

DOI:

10.1007/BF02758379

Web of Science ID:

ISI:000085631800014

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	JAN
Publisher	MAIK NAUKA/INTERPERIODICA
Address	C/O PLENUM/CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Research-Areas	Materials Science
Web-of-Science-Categories	Materials Science, Multidisciplinary
ResearcherID-Numbers	Kuznetsov, Mikhail/N-4007-2014 Tyutyunnik, Alexander/P-2230-2015
ORCID-Numbers	Kuznetsov, Mikhail/0000-0002-4464-0355
Number-of-Cited-References	9
Usage-Count-Since-2013	1
Journal-ISO	Inorg. Mater.
Doc-Delivery-Number	289PU