Crystal structure and magnetic properties of a one dimensional complex oxide Ca3NiMnO6 / Bazuev GV,Zubkov VG,Berger IF,Arbuzova TI // SOLID STATE SCIENCES. - 1999. - V. 1, l. 6. - P. 365-372.

ISSN/EISSN:

1293-2558 / нет данных

Type:

Article

Abstract:

The results of structural refinements and magnetic properties of one-dimensional oxide Ca3NiMnO6 are presented. The structure of Ca3NiMnO6 was solved by Rietveld analysis of powder neutron date in space group R-3c with a=9.1227(9) Angstrom, c=10.5811(17) Angstrom, z=6 (type of K4CdCl6). Infinite chains of MnO6 octahedra and (Ni,Mn)O-6 trigonal prisms sharing faces run parallel ro the c axis. The chains are separated by Ca2+ cations, which are located in a distorted square antiprismatic environment, Magnetic susceptibility obeys the Curie-Weiss law at 300-600 K with mu(eff) value 5.00 mu(B) consistent with the valence cationic combination Ni2+-Mn4+. Magnetic measurements display the antiferromagnetic ordering in Ca3NiMnO6 at 16 K.

Author keywords:

нет данных

DOI:

10.1016/S1293-2558(00)80090-4

Web of Science ID:

ISI:000084083800005

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	AUG-SEP
Publisher	EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
Address	23 RUE LINOIS, 75724 PARIS CEDEX 15, FRANCE
Language	English
Research-Areas	Chemistry; Physics
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Physical; Physics, Condensed Matter
ResearcherID-Numbers	Arbuzova, Tamara/K-1702-2013
ORCID-Numbers	Arbuzova, Tamara/0000-0003-0360-2210
Number-of-Cited-References	8
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	9
Journal-ISO	Solid State Sci.
Doc-Delivery-Number	262UA