New enamine ligands derived from ethyl 2-ethoxymethylidene-3-oxo-3-polyfluoroalkylpropionates and o-phenylenediamine / Kudyakova Yu S.,Goryaeva M. V.,Burgart Ya V.,Slepukhin P. A.,Saloutin V. I. // RUSSIAN CHEMICAL BULLETIN. - 2010. - V. 59, l. 8. - P. 1582-1593.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

Diethyl 2,2' {[}1,2-phenylenebis(aminomethylidene)]bis(3-oxo-3-polyfluoroalkylpropion ates) were synthesized by the condensation of a double excess of ethyl 2-ethoxymethylidene- 3-oxo-3-polyfluoroalkylpropionates with o-phenylenediamine. The use of equimolar ratios of the starting reactants affords ethyl 2-{[}(2-aminophenyl)aminomethylidene]-3-oxo- 3-polyfluoroalkylpropionates from which nonsymmetric biscondensation products were synthesized by the reaction with related reactants containing different polyfluoroalkyl substituent. The copper(II), nickel(II), and cobalt(II) complexes were obtained on the basis of new ligands.

Author keywords:

beta-keto acids; o-phenylenediamine; enamines; ligands; copper(II) complexes; nickel(II) complexes; cobalt(II) complexes; organofluorine compounds TEMPLATE-CONDENSATION; BETA-KETOALDEHYDES; CHELATE COMPLEXES; NICKEL(II); CHEMISTRY

DOI:

10.1007/s11172-010-0281-2

Web of Science ID:

ISI:000285876500016

Соавторы в МНС:

Другие поля

Поле	Значение
Month	AUG
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	TEMPLATE-CONDENSATION; BETA-KETOALDEHYDES; CHELATE COMPLEXES; NICKEL(II); CHEMISTRY
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	saloutin@ios.uran.ru
ResearcherID-Numbers	Burgart, Yanina/T-8025-2017 Kudyakova, Yulia/J-7484-2016
ORCID-Numbers	Burgart, Yanina/0000-0001-6061-2410 Kudyakova, Yulia/0000-0003-0637-1606
Funding-Acknowledgement	Presidium of the Ural Branch of the Russian Academy of Sciences {[}09-P-3-1013]; Russian Foundation for Basic Research {[}10-03-96017]
Funding-Text	This work was financially supported by the Presidium of the Ural Branch of the Russian Academy of Sciences (Program No. 09-P-3-1013) and the Russian Foundation for Basic Research (Project No. 10-03-96017).
Number-of-Cited-References	26
Usage-Count-Since-2013	6
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	702ED