Reactions of 2-arylhydrazono-1,3-dicarbonyl compounds with ethylenediamine / Khudina OG,Burgart YV,Murashova NV,Saloutin VI // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2003. - V. 39, l. 10. - P. 1421-1428.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

2-Arylhydrazono-1,3-diketones react with ethylenediamine to give, depending on the substituents, dihydro-1,4-diazepine derivative or N,N'-ethylenebis(1,3-aminovinyl ketones). Treatment of the latter with nickel(II) or copper(II) acetate results in formation of the corresponding metal chelates. Nickel complexes of N,N'-ethylenebis(1,3-aminovinyl ketones) can also be synthesized from 2-arylhydrazono-1,3-diketones and ethylenediamine on a metal template. Reactions of 2-arylhydrazono-3-oxo esters with ethylenediamine yield N,N'-ethylenebis(3-alkyl-2-arylhydrazono-3-oxopropionamides). Ethyl 2-arythydrazonoacetoacetate reacts with ethylenediamine under mild conditions, affording ethyl 2-p-totylazo-3-{[}2-(2-p-tolylhydrazono-1,3-dioxobutyl-amino)ethylamino] -2-butenoate.

Author keywords:

нет данных

DOI:

10.1023/B:RUJO.0000010558.5476

Web of Science ID:

ISI:000188120200011

Соавторы в МНС:

Другие поля

Поле	Значение
Month	OCT
Publisher	MAIK NAUKA/INTERPERIODICA
Address	C/O KLUWER ACADEMIC-PLENUM PUBLISHERS, 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	saloutin@ios.uran.ru
ResearcherID-Numbers	Burgart, Yanina/T-8025-2017
ORCID-Numbers	Burgart, Yanina/0000-0001-6061-2410
Number-of-Cited-References	17
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	763VB