Synthesis of ethyl 3-oxo-2-(3,4,5-trifluoro-2,6-dimethoxybenzoyl)butyrate / Kisil' SP,Kodess MI,Burgart YV,Saloutin VI // RUSSIAN CHEMICAL BULLETIN. - 2000. - V. 49, l. 6. - P. 1090-1092.

ISSN/EISSN:
1066-5285 / нет данных
Type:
Article
Abstract:
Ethyl acetoacetate was acylated with 3,4,5-trifluoro-2,6-dimethoxybenzoyl chloride to give, for the first time, ethyl 3-oxo-2-(3,4,5-trifluoro-2,6-dimethoxybenzoyl)butyrate and its copper chelate. The title compound was used for the synthesis of 6,7,8-trifluoro-5-hydroxy-2-methylchromone, 1-(3,4,5-trifluoro-2,6-dimethoxyphenyl)butane-1,3-dione, and its copper chelate.
Author keywords:
acylation; beta,beta `-dioxo ester; beta-diketone; Cu-II chelate; chromone SELECTIVE ORTHO-METHOXYLATION
DOI:
10.1007/BF02494900
Web of Science ID:
ISI:000089451000023
Соавторы в МНС:
Другие поля
Поле Значение
Month JUN
Publisher CONSULTANTS BUREAU
Address 233 SPRING ST, NEW YORK, NY 10013 USA
Language English
Keywords-Plus SELECTIVE ORTHO-METHOXYLATION
Research-Areas Chemistry
Web-of-Science-Categories Chemistry, Multidisciplinary
ResearcherID-Numbers Burgart, Yanina/T-8025-2017
ORCID-Numbers Burgart, Yanina/0000-0001-6061-2410
Number-of-Cited-References 10
Usage-Count-Since-2013 2
Journal-ISO Russ. Chem. Bull.
Doc-Delivery-Number 356PE