REACTION OF 2-AMINO-4-IMINO-2-PERFLUOROPENTENE WITH ETHYLENEDIAMINE AND DIETHYLENETRIAMINE / SALOUTIN VI,SKRYABINA ZE,BURGART YV,CHUPAKHIN ON,FONTALTABA M,SOLANS X,FONTBARDIA M // RUSSIAN CHEMICAL BULLETIN. - 1993. - V. 42, l. 10. - P. 1697-1700.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The transamination of 2-amino-4-imino-2-perfluoropentene with ethylenediamine gives the corresponding 6-fluoro-5,7-bis(trifluoromethyl)-2,3-dihydro-1H-1,4-diazepine. The transamination of 2-amino-4-imino-2-perfluoropentene by diethylenetriamine is accompanied by intramolecular nucleophilic substitution of the alpha-fluorine atom to form 1,9-bis(trifluoromethyl)-3,4,6,7-tetrahydro-2H-pyrazino{[}1,2-a]pyrazine whose structure was established by an X-ray structural investigation. Several salts of this bicyclic compound and its complex with BF3 have been described.

Author keywords:

2-AMINO-4-IMINO-2-PERFLUOROPENTENE; BETA-AMINOVINYLIMINE; ETHYLENEDIAMINE; DIETHYLENETRIAMINE; TRANSAMINATION; N-HETEROCYCLES; INTRAMOLECULAR NUCLEOPHILIC SUBSTITUTION

DOI:

10.1007/BF00697043

Web of Science ID:

ISI:A1993NX10100018

Соавторы в МНС:

Другие поля

Поле	Значение
Month	OCT
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013
Language	English
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
ResearcherID-Numbers	Burgart, Yanina/T-8025-2017
ORCID-Numbers	Burgart, Yanina/0000-0001-6061-2410
Number-of-Cited-References	6
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	NX101