INTERACTION OF FLUORINE-CONTAINING 1,3-DICARBONYL COMPOUNDS WITH POLYAMINES / SALOUTIN VI,SKRYABINA ZE,BURGART YV,KISELEVA SV // BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE. - 1992. - V. 41, l. 11, 2. - P. 2046-2050.

ISSN/EISSN:

1063-5211 / нет данных

Type:

Article

Abstract:

In the reaction of fluorinated copper(II) 1,3-diketonates with diethylenetriamine (or triethylenetetramine) in CHCl3, N,N'-bis(1,3-aminovinylketones) are formed in 21-35\% yields. Fluorine-containing 1,3-diketones and 1,3-ketoesters, upon interaction with polyamines without solvent, undergo acid cleavage, forming the corresponding amides. The copper(II) 1,3-ketoesterates are readily cleaved in CHCl3 at 25-degrees-C in excess triethylenetetramine or ethylenediamine.

Author keywords:

COPPER(II) 1,3-DIKETONATES AND 1,3-KETOESTERATES; FLUOROALKYL-CONTAINING 1,3-DIKETONES AND 1,3-KETOESTERS; ETHYLENEDIAMINE; DIETHYLENETRIAMINE; TRIETHYLENETETRAMINE; N,N'-BIS(1,3-AMINOVINYLKETONES); A LIGANDS

DOI:

10.1007/BF00863371

Web of Science ID:

ISI:A1992LL00200002

Соавторы в МНС:

Другие поля

Поле	Значение
Month	NOV
Publisher	PLENUM PUBL CORP
Address	CONSULTANTS BUREAU 233 SPRING ST, NEW YORK, NY 10013
Language	English
Keywords-Plus	LIGANDS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
ResearcherID-Numbers	Burgart, Yanina/T-8025-2017
ORCID-Numbers	Burgart, Yanina/0000-0001-6061-2410
Number-of-Cited-References	8
Doc-Delivery-Number	LL002