Thermal desulfurization of (alkoxymethyl)thiiranes / Nalet'ko S. A.,Pervova M. G.,Gorbunova T. I.,Zapevalov A. Ya,Toporova M. S.,Saloutin V. I. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2014. - V. 84, l. 11. - P. 2120-2124.

ISSN/EISSN:

1070-3632 / 1608-3350

Type:

Article

Abstract:

Reaction of (alkoxymethyl)oxiranes with thiourea in methanol has afforded the corresponding thiiranes, and catalyst-free thermal desulfurization of the products has been studied. The major products of desulfurization are alcohols and alkenes, both in the cases of (polyfluoroalkyloxymethyl)thiiranes and their non-fluorinated analogs. Longer alkyl chain in thiiranes favors formation of alcohols over alkenes formation in the course of desulfurization.

Author keywords:

thiiranes; desulfurization; extrusion of sulfur; alcohol; alkene ALLYL ETHERS; DECOMPOSITION; ALCOHOLS

DOI:

10.1134/S1070363214110139

Web of Science ID:

ISI:000346494400013

Соавторы в МНС:

Другие поля

Поле	Значение
Month	NOV
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3350
Keywords-Plus	ALLYL ETHERS; DECOMPOSITION; ALCOHOLS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	naletko@ios.uran.ru
Number-of-Cited-References	15
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	AW8EU