Oxidation of highly chlorinated benzenes and biphenyls with potassium persulfate in the presence of perfluorinated radicals / Gorbunova T. I.,Pervova M. G.,Panyukova A. A.,Zapevalov A. Ya.,Saloutin V. I. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2013. - V. 83, l. 9. - P. 1678-1686.

ISSN/EISSN:

1070-3632 / 1608-3350

Type:

Article

Abstract:

The interaction of 1,2,3,4-tetrachlorobenzene, 2,4,5-trichlorobiphenyl, 2,5,4'-trichlorobiphenyl, a mixture of 1,2,3- and 1,2,4-trichlorobenzene, and industrial mixtures of polychlorinated biphenyls with potassium persulfate in the presence of potassium perfluorobutyrate has been investigated. The oxidation of highly chlorinated benzenes and biphenyls proceeds with lower conversion than that of the low-chlorinated compounds. The oxidation of the highly chlorinated aromatic substrates is not selective; the reaction mixture contains products of several competitive reactions: addition and elimination of radical species, disproportionation, isomerization, etc. The structures of the products have been determined by means of gas chromatography with mass spectrometric detection.

Author keywords:

AQUEOUS-SOLUTIONS; SULFATE; DECARBOXYLATION; ANIONS; PEROXYMONOSULFATE; MECHANISM; ATOMS; IONS; TCE

DOI:

10.1134/S1070363213090090

Web of Science ID:

ISI:000325704700009

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3350
Keywords-Plus	AQUEOUS-SOLUTIONS; SULFATE; DECARBOXYLATION; ANIONS; PEROXYMONOSULFATE; MECHANISM; ATOMS; IONS; TCE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	gorbunova@ios.uran.ru
Funding-Acknowledgement	Ural Branch of the Russian Academy of Sciences {[}12-M-34-2036]
Funding-Text	This work was financially supported by the Ural Branch of the Russian Academy of Sciences (project no. 12-M-34-2036).
Number-of-Cited-References	25
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	17
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	235GJ