Reactions of perfluoro(2,3-epoxy-2-methylpentane) with o-phenylenediamine and ethylenediamine / Filyakova T. I.,Zapevalov A. Ya.,Kodess M. I.,Slepukhin P. A.,Saloutin V. I. // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2013. - V. 49, l. 3. - P. 350-355.

ISSN/EISSN:

1070-4280 / нет данных

Type:

Article

Abstract:

Perfluoro(2,3-epoxy-2-methylpentane) reacted with o-phenylenediamine and ethylenediamine via cleavage of the C-C bond to produce 2,2,3,3,3-pentafluoro-N-{[}2-(2,2,2-trifluoro-1-trifluoromethylethylamin o)-phenyl]propanamide and 2,2,3,3,3-pentafluoro-N-{[}2-(2,2,2-trifluoro-1-trifluoromethylethylamin o)ethyl]-propanamide, respectively. Presumably, these compounds are formed as a result of rearrangement of intermediate ketone generated by intramolecular haloform-type reaction. According to the NMR and X-ray diffraction data, 2,2,3,3,3-pentafluoro-N-{[}2-(2,2,2-trifluoro-1-trifluoromethylethylamin o)phenyl]propanamide in crystal exists as Z conformer with respect to the amide C-N bond.

Author keywords:

EPOXIDES; THIOUREA; UREA

DOI:

10.1134/S1070428013030068

Web of Science ID:

ISI:000317353500006

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	EPOXIDES; THIOUREA; UREA
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	fc403@ios.uran.ru
Funding-Acknowledgement	Ural Branch of the Russian Academy of Sciences {[}12-P-3-1020]
Funding-Text	This study was performed under financial support by the Ural Branch of the Russian Academy of Sciences (project no. 12-P-3-1020).
Number-of-Cited-References	16
Usage-Count-Since-2013	10
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	122YC